化工催化反应的危险性分析--章仁根的blog

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化工催化反应的危险性分析 | 2010-11-26 9:02:00

催化反应是在催化剂的作用下所进行的化学反应。例如氮和氢合成氨，由二氧化硫和氧合成三氧化硫，由乙烷和氧合成环氧乙烷等都是属于催化反应。
　　催化的火灾危险性：
　　(1)反应操作在催化过程中若催化剂选择的不正确或加入不适量，易形成局部反应激烈；另外，由于催化大多需在一定温度下进行，若散热不良、温度控制不好等，很容易发生超温爆炸或着火事故。
　　(2)催化产物在催化过程中有的产生氯化氢，氯化氢有腐蚀和中毒危险；有的产生硫化氢，则中毒危险更大，且硫化氢在空气中的爆炸极限较宽(4．3％～45．5％)，生产过程中还有爆炸危险；有的催化过程产生氢气，着火爆炸的危险更大，尤其在高压下，氢的腐蚀作用可使金属高压容器脆化，从而造成破坏性事故。
　　(3)原料气原料气中某种能与催化剂发生反应的杂质含量增加，可能成为爆炸危险物，这是非常危险的。例如，在乙烯催化氧化合成乙醛的反应中，由于催化剂体系中常含有大量的亚铜盐，若原料气中含乙炔过高，则乙炔就会与亚铜盐反应生成乙炔铜。乙炔铜为红色沉淀，是一种极敏感的爆炸物，自燃点在260～270℃之间，干燥状态下极易爆炸，在空气作用下易氧化成暗黑色，并易于起火。

By:章仁根 | 阅读全文 | 回复(29) | 引用通告 | 编辑

标签：化工催化反应危险性分析

Re:化工催化反应的危险性分析 | 2010-11-26 9:04:14

分析危险性,落实防范措施,确保生产安全.

By:章仁根 | 个人主页 | 引用 | 返回 | 删除 | 回复

原创 | 2016-9-6 17:56:01

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原创 | 2016-9-28 17:29:51

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原创 | 2016-9-30 12:06:12

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Re:在漫画中识别身边的违章 | 2016-10-8 15:37:13

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Re:在漫画中识别身边的违章 | 2016-10-8 19:23:51

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Re:在漫画中识别身边的违章 | 2016-10-11 18:07:59

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Re:在漫画中识别身边的违章 | 2016-10-12 12:23:05

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Re:在漫画中识别身边的违章 | 2016-10-14 13:16:25

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Re:在漫画中识别身边的违章 | 2016-10-14 14:59:14

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Re:在漫画中识别身边的违章 | 2016-10-15 3:17:35

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Re:在漫画中识别身边的违章 | 2016-10-17 12:18:22

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Re:在漫画中识别身边的违章 | 2016-10-18 2:52:30

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By:yvkmq(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2016-10-19 2:38:53

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By:mqvxb(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2016-10-19 13:51:57

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By:wvlnr(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2016-10-21 2:28:26

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By:euwad(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2016-10-22 21:08:10

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By:fjoqu(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2016-10-22 23:26:17

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By:srgjn(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2016-10-23 8:56:31

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By:vzejm(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2017-2-18 16:40:23

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By:igvzd(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2017-2-18 18:50:52

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By:uqinq(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2017-2-18 23:48:57

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By:nwlos(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2017-2-19 13:43:12

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By:bglnr(游客) | 个人主页 | 引用 | 返回 | 删除 | 回复

Re:在漫画中识别身边的违章 | 2017-2-20 0:03:59

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